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Creators/Authors contains: "Pei, Yuchen"

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  1. ; ; ; ; ; ; ; ; ; ; et al (, Nanoscale)
    The molecular basis for the high cis -alkene selectivity over intermetallic PtSn for alkyne semi-hydrogenation is demonstrated. Unlike the universal assumption that the bimetallic surface is saturated with atomic hydrogen, molecular hydrogen has a higher barrier for dissociative adsorption on intermetallic PtSn due to the deficiency of Pt three-fold sites. The resulting molecular behavior of adsorbed hydrogen on intermetallic PtSn nanoparticles leads to pairwise-hydrogenation of three alkynes to the corresponding cis -alkenes, satisfying both high stereoselectivity and high chemoselectivity. 
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  2. ; ; ; ; ; ; ; (, The Journal of Physical Chemistry C)
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  3. ; ; ; ; ; ; ; ; ; ; et al (, Journal of Catalysis)
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  4. ; ; ; ; ; ; ; ; ; (, Journal of the American Chemical Society)
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  5. ; ; ; ; ; ; ; (, ChemCatChem)